Document Details

Document Type : Article In Journal 
Document Title :
NEW COMPLEXES OF RUTHENIUM(II) WITH THIOSEMICARBAZIDE AND BETA-DIKETONE LIGANDS
NEW COMPLEXES OF RUTHENIUM(II) WITH THIOSEMICARBAZIDE AND BETA-DIKETONE LIGANDS
 
Document Language : Arabic 
Abstract : The reaction of thiosemicarbazide (NH2.NH.CS.NH2) with [Rh(CO)2Cl2]n in THF gives an air stable, off white solid Ru(CO)2Cl2.NH2.NH.CS.NH2. The ligand acts as bidendate and its has been suggested that it coordinates to the metal through N(1) and S atom. Also the salt [Ru(CO)2Cl2]n reacts with an excess of sodium acetylacetonate in THF and gives very stable red solid Ru(CO)2(acac)2xH2O. Similar product is obtained when [Ru(CO)2Cl2]n is treated with acetylacetone in presence of a base such as triethylamine. The complexes were characterised by IR, NMR and elemental analyses. 
Journal Name : JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN 
Volume : 12 
Issue Number : 3 
Publishing Year : 1990 AH  
Added Date : Saturday, June 14, 2008 

Researchers

Researcher Name (Arabic)Researcher Name (English)Researcher TypeDr GradeEmail
أحمد عمر بغلف Researcher  

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